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A coupling reaction or oxidative coupling in organic chemistry is a catch-all for a range of reactions in Organometallic chemistry where two hydrocarbon radicals are coupled with the aid of a metal containing catalyst.

Coupling reactions should be divided into two main classes, there are the cross couplings in which two different molecules react to form one new molecule. For example the nickel chloride catalyzed reaction of an aryl magnesium halide with an aryl halide to form a biaryl.